Insight into vulcanization mechanism of novel binary accelerators for natural rubber
نویسندگان
چکیده
منابع مشابه
Vulcanization and the Properties of Rubber
Rubber is composed of long stringlike polymer molecules, which are pinned together at random points by crosslinks. As the density of crosslinks is increased, the molecules get localized and the system undergoes a phase transition from a liquid to an amorphous solid state. The elastic properties of the resulting solid are very different from those of metals, and are primarily due to changes in t...
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Two silane coupling agents were used for hydrolysis-condensation reaction modification of nanosilica surfaces. The surface characteristics were analyzed using Fourier transform infrared spectroscopy (FTIR). The vulcanization kinetics of natural rubber (NR) + silica composites was studied and compared to behavior of the neat NR using differential scanning calorimetry (DSC) in the dynamic scan mo...
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In the rubber industry, plasticizers for rubber compounds mainly consist of petroleum derivatives. Consequently, the rubber industry is in constant competition with many petroleum consumers. This competition places an economic strain on rubber companies such as HEXPOL RUBBER COMPOUNDING L.L.C. In order to alleviate this strain, natural oil alternatives to petroleum plasticizers are of novel res...
متن کاملThe Cyclization of Natural Rubber
The effects of solvent, temperature, time, weight percent of catalyst on the rate and mechanism of cyclization of natural rubber (NR) was studied in toluene and xylene solutions having tin tetra chloride catalyst (SnCl4). Iodometric titration show, with 8% SnCl4 (based on polymer weight) cyclization occurs, leaving 27.4% of the total unsaturation. Infrared spectra of c...
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– A Landau theory is constructed for the vulcanization transition in cross-linked polymer systems with spontaneous nematic ordering. The neo-classical theory of the elasticity of nematic elastomers is derived via the minimization of this Landau free energy; this neoclassical theory contains the classical theory of rubber elasticity as its isotropic limit. Our work not only reveals the statistic...
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ژورنال
عنوان ژورنال: Chinese Journal of Polymer Science
سال: 2014
ISSN: 0256-7679,1439-6203
DOI: 10.1007/s10118-014-1486-x